( Effective From June – 2009 )
| UNIT NO | TOPIC OF UNIT | PERIOD ALLOTTED | MARKS |
| 01 | WAVE MECHANICS | 16 | 14 |
| 02 | CHEMICAL BONDING | 16 | 14 |
| 03 | 16 | 14 | |
| 04 | 16 | 14 | |
| 05 |
(A) CHEMISTRY OF ELEMENTS OF SECOND AND THIRD TRANSITION SERIES |
16 | 14 |
· Black Body Radiation & Quantum Theory
· Photo Electric effect: Wave particle duality of radiation
· Compton effect
· Basic postulates of Quantum Mechanic
· Operators : Definition, algebra of operators :addition,multiplication,commutative properties, linear operator, commutator
operator, Laplassian operators
· Eigen value and Eigen function
· Rules for satting up of quantum mechanical operators
· Free particle system
· Particle in one dimension box
[Ref. Quantum Chemistry by R.K.Prasad Revised IIIrd Edition Page No.3-5,7,34-37,41,65-68]
Valence Bond Theory : V.B.T for H2+ & H2 ,Comparision Of M.O and V.B Theory.
Molecular Orbital Theory: Introduction, The L.C.A.O method, Bonding, non-bonding and antibonding molecular orbitals, Gerade and
Ungerade orbitals (Symmetry point of view) Bond Order, Homo and Hetero nuclear diatomic molecules like: H2,Li2,B2,N2,O2,F2,CO and
NO CN
[Ref. Valence and molecular structure by Cartmels and Fowels Page No.72-94]
Unit-III (A) Co -ordination Chemistry
1. Elementary idea of Crystal Field Theory
2. C.F.S.E for high Spin and law spin Oh and Td complexes
3. Application of CFT
(i) for determination of colour of complex
(ii) Use of C.F.S.E value
4. Limitation of CFT
5. Isomerism in Complexes
(B) Magnetic properties of Co -ordination Compounds
Types of magnetic behavior
Methods for determining magnetic susceptibility
Spin only formula
L-S coupling& jj coupling
Magnetic properties for 3d-matal complexes
Introduction
Classification of hydrides
Preparation, properties structure and use of diborane.
Bridge bonding in B2H6 (M.O. Approach)
Structure of higher boranes: B4H10, B5H9, B5H11, B6H10, B10H14
Ref : Advance inorganic Chemistry: by Satya parkash, S.Chand Publication VOL.-I page No.819-828
(B) Chemistry of noble gases :
Introduction
Electronic configuration of noble gases
Compounds of noble gases:
(i) Non-real compounds prepared by different methods
(ii) True compounds XeF2, XeF4 XeF6 XeOF2 XeO3 XeOF4
Unit –V (A) Chemistry of elements of second and third transition series.
General characteristics, comparative treatment with 3d- analogues in respect of ionic radii, oxidation state, magnetic behavior, oxides, halides, and complex compounds of Pt and Ag.
Introduction, name and structure of deuterium, preparation of D2O (Heavy water), physical and chemical properties of Deuterium.
| UNIT NO | TOPIC OF UNIT | PERIOD ALLOTTED | MARKS |
| 01 | 16 | 14 | |
| 02 | 16 | 14 | |
| 03 | 16 | 14 | |
| 04 | 16 | 14 | |
| 05 | 16 | 14 |
UNIT – I
1. Proton acids and bas
Lewis acids and bases
2. Scales of acidity – basicity
3. Resonance effect ,
4. Drawing resonance structures and the conditions for
resonance
5. Effect on changes of hybridization on acidity and basicity
6. Inductive and electronic effects
7. Steric effects and effects by hydrogen bonding
(B) Reaction & Reaction Mechanism With Application :
1. Pinacol- pinacolone rearrangement
2. Bayer-villiger rearrangement
3. Benzoin condensation
4. Aldol condensation
5. Perkin’s reaction
6. Clammenson reduction
7. Wolf-kishner reduction
UNIT – II
(B) Polynuclear Aromatic Hydrocarbons :
1. Fused ring compounds
2. Nomenclature of naphthalene & anthracene
3. Structure of naphthalene & anthracene
4. Synthesis of naphthalene & anthracene by Haworth Synthesis
5. Reaction of naphthalene & Anthracene
(i) Oxidation
(ii) Reduction
(iii) Dehydrogenation
(iv) Nitration
(v) Halogenation
(vi) Sulphonation
(vii) Friedel – Craft reaction
6. Synthesis of α- & β- substituted Naphthalene derivatives (Howath synthesis only)
7. Synthesis of 9 & 9-10 substituted Anthracene derivatives (Howath synthesis only)
1. Nomenclature
2. Physical properties
3. Methods of preparation
4. Chemical properties of cycloalkanes
5. Orbital picture of angle strain, Bayer’s strain theory
6. Heats of combustion and relative stabilities of cyclohexane
7. Strainless ring theory
UNIT – III
1. Glycosides:
(i) Introduction
(ii) Natural glycosides
(iii) Introduction of glycosides ( Arbutin, Salicin, Indican
and Amygdalin )
2. Mutarotation
3. Cyclic structure of D ( +) glucose
4. Determimation of size of the ring
5. Conformational stability of α and β – anomers of D(+) glucose
1. Classification
2. General methods of structure determination
3. Isoprene rule
4. Constitution of Citral and α – Terpeneol with synthesis
UNIT – IV
1. Introduction
2. Nomenclature
3. Molecular orbital picture and aromatic characteristics of Pyrrole,Furan,Thiophene and Pyridine
4. Method of synthesis and chemical reactions with particular emphasis on the mechanism of electrophilic substitution
5. Basicity of Pyridine, Piperidine and Pyrrole
Amino acids :
1. Structure
2. Classification and nomenclature
3. Dipolar ion structure and isoelectric point
4. Synthesis of amino acids (Gabriel Phthalimide,Straker,Fisher-Malonic ester)
5. Reaction of Amino acid
Peptides :
6. Geometry of peptide linkage
7. Synthesis of peptide (Bergmann Method,Shehan Method)
8. Determination of structure of peptide by terminal residue analysis
UNIT - V
1. Introduction of ultraviolet – visible absorption spectroscopy
2. Absorption laws ( Beer – Lambert law )
3. Molar absorptivity
4. Presentation and analysis of UV – spectra
5. Types of electronic transitions
6. Effect of conjugation
7. Concept of Chromophore and Auxochrome
8. Bathochromic, Hypsochromic, Hyperchromic and Hypochromic shifts
9. Woodward – fisher rules
10. Problems of conjugated enes,enones and aromatic ketones,aldehydes,acids and esters using empirical rules
Books Suggested (Organic)
(1) Organic Reactions and their mechanism. P.S.Kalsi, New age interntional publishers.
(2) Text book of organic chemistry, P.S.Kalsi, New age interntional publishers.
(3) Organic chemistry Vol. I & II, S.M.Mukherji, S.P.Singh, R.P.Kapoor
(4) Reactiom mechanisn in Organic chemistry S.M.Mukherji, S.P.Singh.3rd ed. Macmillan
(5) Reaction mechanism and Reagents in Organic chemistry. Gurdeep R. Chatwal 4th ed. Himalaya public. House.
(6) Text book of Organic chemistry, Arun Bahl, B.S.Bahl, S.Chand.
(7) Organic chemistry Morrison and Boyd. 6th ed. Pearson Education-2003.
(8) Organic chemistry T.W.Graham Solomons. 4th ed. John Wilay,1998.
(9) Organic Spectroscopy by P.S.Kalsi.
(10) Organic chemistry by I.L.Finar
(11) Organic chemistry by Jagadambasingh
| UNIT NO | TOPIC OF UNIT | PERIOD ALLOTTED | MARKS |
| 01 | 16 | 14 | |
| 02 | 16 | 14 | |
| 03 | 16 | 14 | |
| 04 | 16 | 14 | |
| 05 | 16 | 14 |
UNIT – I
Phase in Equlibrium
1. Clapeyron-clausius equation
2. Integrated form of clapeyron-clausius equation
3. Application of clapeyron-clausis equation from various phase in equilibrium
Trotan law
Craft equation
Equation in Boiling Point. (Kb)
Depression of freezing point. (Kf)
Partial molar Properties
4. Partial molar free energy
5. Concept of Chemical Potetial
6. Gibbs-Duhem equation
7. Variation of chemical potential with temperature and pressure
8. Duhem-Margules equation
9. Chemical potential of an ideal gas in a mixture of ideal gases
( I ) Thermodynamic functions of mixing of an ideal gases
1. Free energy
2. Entropy
3. Heat (Enthalpy)
4. Volume
( II ) Numericals
UNIT II
1. Only Introduction
Electrolysis, Ionic Equilibrium, Resistance, Conductance, Specific Conductance, Equivalent Conductance, Molar Conductance,
Equivalent Conductance at Infinite Dilution
2. Kohlraussch’s Law and its applications
3. Application of Conductivity Measurement
4. Conductometric Titration
Measurement of Conductance
Advantage of Conductometric Titration
5. Types of Conductrometric Titration
( i ) Acid – Base Titration
1. Strong Acid Vs Strong Base
2. Strong Acid Vs Weak Base
3. Weak Acid Vs Strong Base
4. Weak Acid Vs Weak Base
5. Strong Acid + Weak Acid Vs Strong Base
( ii ) Replacement Titration
( iii ) Precipitation Titration
( iv ) Complexometric Titration
6. Ostwald’s Dilution Law and its limitations
7. Dissociation Constant
8. Common ion effect and its applications
9. Solubility Product and Solubility
10. Transport Number
( i ) Determination of Transport Number
1. Hittorf’s Method
2. Moving Boundary Method
11. Numericals
1. Introduction of terms
Oxidation, Reduction, Redox, Anode, Cathode, Electrode, Half Cell, Oxidation & Reduction Potential
2. Electrochemical cell (Galvanic Cell) & Representation of Cell
3. Electrochemical Series and its Significance
4. Nernst Equation of Cell EMF and single Electrode Potential
5. Describe the Electrode
1. Metal – Metal ion Electrode
2. Standard Hydrogen Electrode
3. Calomel Electrode
4. Weston Standard Electrode
6. Application of cell potential
1. Calculation of equilibrium – constant
2. Calculation of free energy
6. Numerical
UNIT III
1. State Gibb’s phase rule
2. Statement and meaning of the terms with examples
( i.) Phase
( ii.) Component
( iii.) Degree of freedom
3. Derivation of Gibb’s phase rule
4. Phase Equilibrium of one component system
( i.) The water system
( ii.) The CO2 system
( iii ) The Sulphur system
5. Reduced phase rule of condensed system
6. Two component system
( I ) Solid – Solid system
1. Ag – Pb system
2. Zn – Mg system
( II ) Solid – Gas system
1. CuSO4 – H2O(g) system
7. Steam Distillation
8. Numericals
1. Nernst distribution law and its limitations
2. Thermodynamic derivation
3. Deviation from distribution law due to molecular complexity
( i.) The solute undergoes association in one of the solvents
( ii.) The solute undergoes dissociation in one of the solvents
( iii ) The solute enters into chemical combination with one of the solvent
4. Applications of distribution law
5. The process of Extraction
6. Numericals
UNIT-IV
1. Effect of Temperature on rate of reaction (Arrahenius equation )
2. Concept of Activation energy
3. Theories of reaction rates
1. Collision theory
2. Transition state theory
( I ) Application of transition state theory
1. Unimolecular reaction
2. Reaction in solution
3. Reaction in Gas
4. Entropy of activation
( II ) Comparison of collision and transition state theory
4. Theories of Unimolecular reaction
5. Lindemann’s theory
6. Numericals
1. Only introduction
( i ) Difference between True solution, Colloidal solution and suspension
( ii ) Types of colloid
( iii ) Classification of colloid
2. Difference between Lyophilic and Lyophobic colloids
3. Properties of colloidal solution
1. Optical properties (Tyndall effect, Brownian movement)
2. Electrical properties (Electroosmosis and Electrophoresis)
3. Electro-Kinetics properties (Zeta potential)
4. Schulze-Hardy rule
5. Gold number
6. Gels
7. Emulsions
8. Molecular weight of colloid
1. Osmotic Pressure system
2. Donnan membrane equilibrium
3. Ultrasentrifuse method
9. Importance of colloid
UNIT V
(A) Physical Properties of Liquid
1. The vacancy theory of liquid
2. Vapour – Pressure
3. Surface tension
( i ) Measurement of Surface tension by stalagmometer
( ii ) Perachore and its applications
4. Viscosity
( i ) Measurement of viscosity by Oswald - viscometer
5. Refractive index
( i ) Specific refraction
( ii ) Molar refraction
( iii ) Measurement of Refractive index by Abbe’s refractometer
6. Optical activity
( i ) Measurement of Optical activity by Polarimeter
7. Numericals
Difference between isotropic and anisotropic
Space lattice
Unit cell
Calculation of number of atoms per unit cell
Types of cubic lattice
Miller Indices
Seven crystal systems( Bravais lattices)
Geometry of solid
X-Ray diffraction by crystals
Bragg equation
Powder method for X-Ray diffraction
Determination of crystal structure of NaCl, KCl and CsCl
Numericals
Reference Books
Physical Chemistry
1. Advance physical chemistry by Gurdeepraj
2. Physical chemistry (Questions and Answers) by R.N. Madan, G.D. Tuli, S.Chand
3. Principal of physical chemistry, by Puri, Sharma, Pathania
4. Chemical thermodynamics by R.P.Rastogy and R.R.Misra
5. Essentials of physical chemistry by B.S.Bahal, Arun Bahal, G.D.Tuli
6. Physical chemistry by P.W.Atkins, 5th ed. , Oxford, 1994, 7th ed 2002
7. Physical chemistry by R.A. Alberty and R.J.Silbey, John Wiley, 1995
8. Physical chemistry by G.H.Barrow, 5th ed., MacGraw Hill,1988, 6th ed., 1996
9. Physical chemistry by W.J.Moore, 4th ed., Orient Longmans, 1969.
This Syllabus is to be completed by assigning three laboratory session per week, each of three periods.
The number of students in the laboratory batch should not exceed fifteen(15)
The medium of instruction will be English in Laboratory Course.
Inorganic Chemistry
(A) Inorganic qualitative analysis: (Minimum Ten)
Inorganic mixture should comprise of four radicals. Arsenate, arsenite, Borate and insoluble phosphates are not to be given. ( Do not deduct any marks for wrong radical)
(B) Volumetric Analysis
(I) To determine the amount of Zn by EDTA Method.
(II) To determine the amount of Ni by EDTA Method.
(III) To determine the amount of Cu by Iodometry Method.
(IV) To determine the amount of Fe by Redox titration.
Organic Chemistry
(A) Separation of Organic Mixture : ( Minimum 10 Mixtures)
Organic mixtures are to be prepared only from organic substance specified below :
Solid – solid ( Water insoluble)
Acids : Bases :
Salicyclic acid o-,m-,p- nitro aniline
Benzoic acid p- toluidine
Cinnamic acid Di-phenyl amine
Phthalic acid
Phenols : Neutrals :
α-naphthol Naphthaline
β –naphthol Anathracine
m-dinitro benzene
Acetanilide
Benzamide
(B) Estimation of Functional Groups :
(I) To determine the no. of -COOH group present in a given unknown Acid.
(II) To determine the amount of Aniline by Brominating Method.
(III) To determine the amount of Phenol by Brominating Method.
(IV) To determine the amount of Glucose by oxidation Method.
Physical-chemistry Practicals
1. Conductrometric titration:- HCl / CH3COOH Vs NaOH
2. Conductrometric titration:- HCl Vs NH4OH
3. PH.- metric titration:-
a. Calibration of PH - meter by 4 - PH buffer
b. HCl Vs NaOH
4. Determine the Dissociation constant of the acid of mixtures of CH3COONa and CH3COOH by determine the PH
5. Determine the molar concentration of unknown solution from given KMnO4 solution by colourimetry
6. Determine the molar concentration of unknown solution from given K2Cr2O7solution by colourimetry
7. Determine the specific refraction and molar refraction of the given liquid A, B and mixture C (A+B) and calculate the percentage
composition of A and B in the mixture C.
8. Determine the molar refraction CH3COOC2H5 ,CH3COOC3H7 and CH3COOC4H9 and show the constancy of reaction equivalent of
-CH2 - Group
9. To determine the viscosity of a different mixture of liquid A and B and determine the percentage composition of unknown mixture by
graphical method.
10. To determine the surface tension and compare cleaning-efficiency of two samples of a detergent or soap with stalagmometer.
11. To study kinetic reaction of decomposition of H2O2 catalysis by iodine ion (Clock reaction)
12. To determine the equilibrium constant of I2 in water and CCl4 /CHCl3 by distribution method
13. Find the solubility and heat of solution of the given organic acid at two different temperatures
14. To draw the phase diagram of the binary system Diphenyl-amine and α-naphthol and find the eutectic temperature.
A. Study of lower group's of plants
A1 - Bacteriology
A2 - Algology
A3 - Mycology
A4 - Bryology
A5 - Pteridology
B. Plant Pathology C. Plant Morphology
D. Plant Taxonomy E. Plant anatomy
F. Plant Physiology G. Economic Botany
Unit - I Study of Lower groups of Plants
A1 Bacteriology
(i) Structure of Bacterial cell
(ii) Economic importance of Bacteria
A2 Algology
(i) Classification, habitat, Morphology, reproduction and life cycle of the following :
Cyanophyceae : Oscillatoria
Chlorophyceae : Oedogonium
A3 Mycology Classification, habitat, morphology, reproduction and life
cycle of the following :
Phycomycetes : Rhizopus
Ascomycetes : Yeast
A4 Classification,habitat, morphology, reproduction and life history of the following: Hapaticopsida: Riccia
A5 Classification, habitat, morphology, reproduction and life cycle of the following:
Sphenopsida : Equisetum
Unit - II ( Plant Pathology and Economic botany)
Plant Pathology
(i) Introduction
(ii) scope
(iii) General account of the following plant disease :
Citrus canker, Puccinia on Wheat, Ustilago on Jawar
Economic botany :
(1) Food Plants
(i) Introduction
(ii) Origin-history, cultivation and Economic importance of :
(a) Cereals : Rice, Wheat, Maize
(b) Pulses : Cajanus cajan (Pigeon Pea)
(c) Vegetables : Potato, Brinjal, Tomato
Unit - II
1. Economic Botany
(d) Oilseeds : Ground nut, Mustard
(e) Fruits : Mango, Lemon
2. Medicinal Plants Withania, Roulfia
Unit _ III (Plant Morphology and Taxonomy)
C Plant Morphology
(i) Study of various plants of plant body.
(ii) Modification of various parts plantbody :
(a) Root : For : Storage of food, assimilation; support and Reproduction.
(b) Stem : For : Vegetative propogation storage of Food support
(c) Leaf : For : Protection, Tendril, Food storage Reproduction.
(iii) Flower : Explaination of flower.
Various parts of flower Unisexual and bisexual flower Aestivation.
Inflorescence : Explanation
Racemose : Raceme, spike
Cymose : Biparous cyme and Monochasial cyme
Fruit : Explanation of : Simple, Aggregate and composite fruits
Simple : Dry : Achene, Legume, siliquat, capsule
Fleshy : Berry and Drupe
D Plant Taxonomy :
1. Introduction
2. Classification : Introduction of Bentham & Hooker's System.
3. General character of the following families :
Brassicaceae, Malvaceae, Rutaceae, Vitaceae, Myrtaceae, Apocyanaceae, Lamiaceae (Labiatae), Amaranthaceae, Amaryllidaceae, Graminae (Poaceae)
Unit - IV (Plant Anatomy)
E Plant Anatomy :
1. Structure of plant cell : Eukaryotic and Prokaryotics-cell
2. Meristem : Characters
Apical cell theory
Histogen theory and Tunica corpus theory
3. Types of vascular bundles
4. Conducting tissues : structure, function and elements Xylem and Phloem
5. Secondary Growth :
Unit - 4
E Plant Anatomy :
5. Secondary Growth :
(a) Dicot root : Tinospora aerial root
(b) Dicot stem : Cucurbita, Capparis aphylla
(c) Monocot stem Dracaena
Unit - 5
F Plant Physiology :
1. Absorption of Water and minerals
2. Osmosis and Plasmolysis, Diffusion , Imbibition
3. Transpiration -
(a) Process of transpiration
(b) Factors affecting rate of transpiration
(c) Transpiration is necessary evil.
4. Ascent of Sap : Vitll theories Physical forces theories
5. Photosynthesis :
(a) Introduction (b) Location
(c) Raw materials (d) Water and CO2 are used
(e) Chlorophyll is necessary (f) Light energy is stored
(g) Oxygen a liberated (h) Carbohydrates are formed
(i) Concept of limiting factors to be discussed in short
The Proposed New course in chemistry for under Graduate classes are redesigned in accordance with
New Education Policy. The New course is based on Model curriculum of the University Grants commission.
Its Objectives are as under :
1. To meet the growing demands of specialization and advanced courses in applied science.
2. To help the colleges to update and modernize their Laboratories.
3. To redesign the courses with special emphasis on local requirements, environment and to link the
courses, with requirements of the industries and research.
University Examination : (Chemistry Theory) :
The will be three papers of theory at the University examination :
|
Theory (Written) |
Duration |
Marks |
|
|
Paper |
External |
Internal |
|
| Chemistry - III |
3 Hours |
70 |
30 |
| Chemistry - IV |
3 Hours |
70 |
30 |
| Chemistry - V |
3 Hours |
70 |
30 |
| Practical |
7 Hours |
105 |
45 |
University Paper :
|
Question Number |
Number of Units for the question |
Marks for Questions |
| 1 | 1 | 12 |
| 2 | 2 | 12 |
| 3 | 3 | 12 |
| 4 | 4 | 12 |
| 5 | 5 | 12 |
| 6 | 1 to 5 | 10 |
Question - 1 to 5 To be set from unit with internal option. Each question will have two sub questions (a) and
(b), details as under :
Theory Question - 6 marks
Theory / Problem / Numerical - 6 marks
Question - 6 Will have 10 objective questions. All questions will be compulsory. Each will have one mark.
University Examination : (Chemistry Laboratory course) :
|
Laboratory course |
Duration |
Marks |
|
| External | Internal | ||
|
Chemistry Practical |
14 Hours |
105 |
45 |
First Day : 10:00 to 5.30 (Including 30 min. recess)
(A) Gravimetric / Qualitative analysis 3 Hrs-30 min.
22 + 03 (Viva)
(B) Volumetric / Organic Estimation 3 Hrs-30 min.
12 + 03 (Viva)
(C) Questions pertaining to Laboratory course (Written test of 10 questions) 10 Marks
Second day :
(D) Physical Experiment 3 Hrs-30 min.
22 + 03 (Viva)
(E) Organic Separation of Mixture 3 Hrs-30 min.
22 + 03 (Viva)
(F) Journal : 5 Marks
Standard of passing for the Second year B.Sc. Examination :
To pass the examination candidate must Obtain aggregate 36% of marks in chemistry Theory and also in Laboratory course exercise (Practical separately).